Hello.
iButton is used for authorization. So it cannot really be used as You described as iButton is used to turn scenario OFF (because authorization is successful) rather than ON.
https://community.teltonika-gps.com/?qa=blob&qa_blobid=15529389016738164637
If configured like this and Ignition source is set to DIN1
I would work like this (assuming relay is installed):
When driver tries to turn on Ignition, DOUT 1 gets turned on which prevents it, and driver has authorize itslef via iButton. So iButton gets read via reader and if its ID is authorized, meaning it is in the list authorized ID list (list can be found on 1-wire tab in configurator), driver gets authorized and DOUT 1 gets turned off, which allows driver to turn on Ignition.
If there are more questions regarding this, please ask.
Best Regards